
Self-cleaning glass is a type of glass that uses a special coating to repel water and dirt, making it easier to clean. This coating is typically made of a thin layer of titanium dioxide.
This technology was first developed in the 1990s by a team of scientists at Corning, Inc. They discovered that by applying a thin layer of titanium dioxide to the surface of the glass, they could create a self-cleaning effect.
The self-cleaning effect is achieved through a process called photocatalysis, where the titanium dioxide coating breaks down dirt and grime when exposed to sunlight. This process is completely chemical and doesn't require any additional cleaning agents.
As a result, self-cleaning glass is perfect for high-traffic areas or locations where cleaning is difficult.
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What Is Self-Cleaning Glass?
Self-cleaning glass is not just a fancy term for regular glass. It has a special coating that makes it self-cleaning.
The coating is made of titanium dioxide, a white, powdery compound that's also found in paint, toothpaste, and other bright white things. This thin coating is only 10-25 nanometers deep, which is incredibly thin.
This thin coating reduces the light passing through the glass by no more than 5 percent, so it won't affect the amount of natural light coming into your home.
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History and Development
Self-cleaning glass has a fascinating history that dates back to 2001. Pilkington Glass announced the development of the first self-cleaning windows, Pilkington Activ™.
These windows were made possible by a thin transparent layer of titanium dioxide, which is a key component in many self-cleaning glass products. This coating acts to clean the window in two stages using photocatalysis and hydrophilicity.
Discovery of Behavior
The discovery of self-cleaning behavior in glass is a fascinating story that dates back to the development of the first self-cleaning glass.
The first self-cleaning glass was based on a thin film titania coating, which was applied using a process called spin coating of organo-titanate chelated precursor.
This coating was made from a chemical called titanium iso-tetrapropoxide chelated by acetylacetone, and it required heat treatment at elevated temperatures to form the anatase phase.
The glass cleans itself in two stages: the photocatalytic stage breaks down organic dirt using ultraviolet light, making the glass superhydrophilic, and the superhydrophilic stage allows rain to wash away the dirt, leaving almost no streaks.

Sodium might diffuse from the glass into the nascent titanium dioxide, causing a degradation in the hydrophilic/catalytic effect unless preventive measures are taken.
The first commercial product, Pilkington Activ, was announced in 2001 by Pilkington Glass and used a thin transparent layer of titanium dioxide.
This coating acts to clean the window in two stages, using two distinct properties: photocatalysis and hydrophilicity.
Patents
Patents have played a significant role in the development of photocatalytic glass.
The first patent we see is from 1997, for self-cleaning glass and method of making thereof, by Yair Haruvy et al.
In 2000, Hiroshi Nakashima et al patented a photocatalytic glass pane equipped with a light source for activating the same.
The 2012 patent by Maarten Marinus Johannes Wilhelmus Van Herpen for Koninklijke Philips Electronics N.V. describes self-cleaning surfaces with built-in LEDs for stimulating the photocatalyst.
Here are some key patents in the development of photocatalytic glass:
- Self-cleaning glass and method of making thereof by Yair Haruvy et al, February 27, 1997.
- Photocatalytic glass pane equipped with light source for activating same by Hiroshi Nakashima et al, for Central Glass Company, Limited, April 25, 2000.
- Self-cleaning system and window-glass by Maarten Marinus Johannes Wilhelmus Van Herpen for Koninklijke Philips Electronics N.V., April 3, 2012.
- Self-cleaning protective coatings for use with photovoltaic cells by Chris M. Gronet and James K. Truman, Solyndra LLC, January 1, 2013.
- Self-cleaning surface coating (photocatalysis) by Rudolf Gensler et al, Siemens AG, February 5, 2013.
- Method of coating glass by John Andrew Ridealgh et al, for Pilkington Group Limited, August 15, 2013.
Titanium Dioxide Applications
Titanium dioxide has become the go-to material for self-cleaning windows and surfaces due to its unique properties.
It's highly efficient at photocatalysing dirt in sunlight, reaching a superhydrophilic state, and is non-toxic and chemically inert in the absence of light.
This makes it an ideal choice for self-cleaning applications, especially considering its affordability and ease of handling.
The International Commission on Glass has been working on setting up test methods for evaluating photocatalytic self-cleaning coatings on glass since 2001.
Titanium dioxide-based glass has some limitations, however, and cannot decompose thick non-transparent deposits like paint or silicone.
But for everyday use, it's perfect for keeping your screens clean, and it's great for applications like computer monitors and PDA screens where fingerprints are a nuisance.
Here are some potential applications for titanium dioxide:
- Cleaning
- Glass coating and surface modification
- Glass applications
- Smart materials
How It Works
Self-cleaning glass is a game-changer for homeowners and businesses alike. The magic behind it lies in the titanium dioxide coating that makes chemical reactions happen when exposed to ultraviolet light.
This coating is a photocatalyst, which means it uses light energy to break down organic dirt into smaller pieces that are easily washed away by rain or a light rinse. The process is similar to what happens in photocatalytic air purifiers.
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The titanium dioxide coating also makes the glass hydrophilic, or "water-loving", which means water molecules spread evenly across the surface in sheets, rather than forming droplets. This sheeting action drastically reduces water spots and streaks, and helps maintain a crystal-clear appearance.
Here's a step-by-step breakdown of how the coating works:
- Ultraviolet light hits the titanium dioxide coating, releasing electrons that break down water molecules into hydroxyl radicals.
- These hydroxyl radicals attack the organic dirt, breaking it down into smaller pieces.
- The glass becomes hydrophilic, allowing water to spread evenly across the surface.
- When rain hits the glass, it spreads across it like a great big cloth, wiping down the dirt and grime.
The result is a self-cleaning glass that requires minimal maintenance and upkeep. In fact, the titanium dioxide coating remains effective for the life of the window, reducing the need for chemical cleaning agents and manual window washing.
Benefits and Advantages
Self-cleaning glass is a game-changer for anyone who's tired of scrubbing away at dirty windows. It's a permanent self-cleaning coating that lasts the lifetime of a window.
With self-cleaning glass, you can say goodbye to frequent window cleaning bills. In fact, ongoing cost savings are one of the biggest advantages of this type of glass.
But how does it work? The coating creates a sheeting effect that helps to repel dirt and grime, making it easier to keep your windows clean. And, as a bonus, it's kinder to the environment with a less frequent use of water and detergents.
Here are some key benefits of self-cleaning glass:
- A permanent self-cleaning coating that lasts the lifetime of a window
- Glass stays cleaner for longer
- Ongoing cost savings with reduced window cleaning bills
- Clear view outside even when it’s raining, thanks to the sheeting effect
- Kinder to the environment with a less frequent use of water and detergents
- Less dirt and grime adheres to the glass so any cleaning is quick and easy
- Perfect for your conservatory roof and other hard-to-reach areas that are difficult to clean
It's worth noting that self-cleaning glass isn't a solution for cleaning windows all year round. You'll still need to wipe down your windows with a wet cloth every now and again. However, it will make your windows significantly lower maintenance than they otherwise would be.
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Types of Coatings
Self-cleaning glass is a game-changer for anyone who's ever struggled with streaks and water spots on their windows. There are several types of coatings that make this technology possible, and understanding the differences between them can help you choose the right one for your needs.
Hydrophilic coatings cause water to spread evenly across the surface in sheets, reducing water spots and streaks. This type of coating is perfect for areas with high humidity or heavy rainfall.
Hydrophobic coatings, on the other hand, repel water, causing it to form beads that roll off the surface. This is great for areas with low rainfall or for people who live in dry climates.
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Photocatalytic coatings actively break down organic substances on the glass surface, using natural sunlight to initiate a chemical reaction. This type of coating is ideal for urban areas where air pollution can accumulate on the surface of the glass.
Photocatalytic self-cleaning glass uses a combination of titanium dioxide and sunlight to break down dirt on the glazing. This coating is strong and has a long lifespan, making it a great choice for anyone who wants a low-maintenance solution.
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Maintenance and Care
Self-cleaning glass is a game-changer for homeowners, but it still requires some basic maintenance to keep it looking its best.
You won't need to clean your self-cleaning glass as often as regular glass, but it's still important to remove any hard water spots that may form.
To do this, simply spray a mixture of two drops of detergent to 24 ounces of water on the hard water stains, let it sit for a minute, and then wipe it off with a clean cloth.
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No Necessary

No Cleaning Necessary with Self Cleaning Glass, making maintenance a breeze.
Our self-cleaning glass windows require no cleaning, a huge advantage for homeowners.
We sell and install a wide range of double glazed UPVC windows, including casement, sliding sash, and tilt and turn windows.
All of our windows are manufactured to the highest standards and installed by our team of expert installers.
This attention to detail ensures our windows are not only self-cleaning but also have high thermal performance.
Our expert installers take pride in their work, ensuring a seamless installation process.
Remove Hard Water Spots from Windows
Removing hard water spots from windows can be a real challenge, but fortunately, there's a simple solution. If you have self-cleaning windows, you're in luck.
To remove hard water spots, you'll need a mixture of two drops of detergent to 24 ounces of water. Spray the mixture on the hard water stains and let it sit for a minute.
After a minute, wipe off the hard water spots with a clean cloth. This should leave your windows streak-free and looking like new.
It's worth noting that self-cleaning windows work by making water "water-loving" rather than "water-hating". This means that when rain hits a dirty self-cleaning window, it spreads across it like a cloth and wipes it clean.
Here's a quick rundown of the steps to remove hard water spots:
- Spray a mixture of 2 drops of detergent to 24 ounces of water on the hard water stains.
- Let the mixture sit for 1 minute.
- Wipe off the hard water spots with a clean cloth.
By following these simple steps, you can keep your self-cleaning windows looking their best and enjoy the benefits of a low-maintenance cleaning solution.
Comparison and Options
Self-cleaning glass is a game-changer for commercial building owners and facility managers. It reduces maintenance costs, improves aesthetics, and contributes to a more sustainable footprint.
There are several leading brands that offer self-cleaning and low-maintenance glass options, including Saint-Gobain, Guardian Glass, AGC Glass, Pilkington, and Vitro Architectural Glass. These companies have developed a wide range of glass solutions, including self-cleaning and low-maintenance coatings.
If you're considering a new build or an upgrade to existing glass, consider using a low-maintenance glass that was manufactured with these coatings already integrated. This will ensure the best results and optimal performance.
The main types of self-cleaning coatings are hydrophilic, hydrophobic, and photocatalytic coatings. These are typically integrated during the manufacturing process for new glass, but there are some treatments that can be applied to existing installations.
Here are some of the leading brands mentioned earlier:
- Saint-Gobain
- Guardian Glass
- AGC Glass
- Pilkington
- Vitro Architectural Glass
To find out how these glass options can be incorporated into your new or existing build, it's best to consult with the experts. They can help you find a solution that works for your facility and provides the best results.
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Frequently Asked Questions
What are the disadvantages of self-cleaning glass?
Self-cleaning glass has a special coating that can be damaged by improper cleaning tools, reducing its effectiveness. Be cautious when cleaning self-cleaning glass to avoid scratching the coating.
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